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Content

Chemistry


Chemistry



SHOW ME SCIENCE ADVANCED - CHEMISTRY & PHYSICS: CHEMISTRY - PERIODIC TABLE OF THE ELEMENTS PART V - UNUNSEPTIUM AND UNUNTRIUM

This program looks at the most recently discovered elements (including Ununseptium and Ununtrium) and the type of commitment and research that is required to make such discoveries. We introduce students to precious elements such as gold, silver and copper and illustrate how "The Big Three" were instrumental in the development of ancient and modern civilizations. Careers in chemistry and element research are highlighted in this dynamic program.

DVD (Closed Captioned) / 2018 / (Grades 6-12) / 11 minutes

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SHOW ME SCIENCE ADVANCED - CHEMISTRY & PHYSICS: CHEMISTRY - PERIODIC TABLE PART IV - IRON, ZINC, SELENIUM

The periodic table organizes elements by an atomic number, based on the amount of protons in each elements nucleus. Other factors include electron configuration and recurring chemical properties. Elements are listed in order of increasing atomic number along with its chemical symbol in each box. The elements iron, zinc and selenium help promote health and fight disease and have commercial uses. Iron zinc and selenium, which happen to exist naturally, are also referred to as trace minerals because humans need only small amounts of them.

DVD (Closed Captioned) / 2018 / (High School or above) / 11 minutes

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SHOW ME SCIENCE ADVANCED - PHYSICAL SCIENCE: BIOLOGY & CHEMISTRY - THE SCIENCE OF FORENSICS

Anthropometry is the science that defines physical measures of a persons size, form, and functional capacities. Forensic science (often shortened to forensics) is the practical application of science to matters of the law. In criminal law, forensics science can help prove the guilt or innocence of the defendant. In civil actions, forensics can help resolve a broad spectrum of legal issues through the identification, analysis and evaluation of physical evidence. This program will discuss how new innovations and discoveries in forensic technology have important scientific applications beyond law.

DVD (Closed Captioned) / 2018 / (High School or above) / 11 minutes

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SHOW ME SCIENCE ADVANCED - TECHNOLOGY: CHEMICAL ENGINEERING COMPOSITES

Composite materials (also called composition materials or shortened to composites) are materials made from two or more constituent materials with significantly different physical or chemical properties, that when combined, produce a material with characteristics different from the individual components. This is an extremely broad definition that holds true for all composites, however, more recently the term "composite" describes reinforced plastics. This program will explain how composites work and what the future holds for these amazing materials.

DVD (Closed Captioned) / 2018 / (High School or above) / 11 minutes

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SHOW ME SCIENCE ADVANCED - TECHNOLOGY: CHEMISTRY METALLURGY

Metallurgy is the study of the extraction, refining, alloying and fabrication of metals and of their structure and properties. Metallurgy can be described as a sub-set of materials science? - the study of physical and chemical behavior of metals and alloys. This program discusses metals role in our control of the environment. Advances in agriculture, warfare, transport, even cookery are impossible without metal, as was the entire Industrial Revolution - from steam to electricity.

DVD (Closed Captioned) / 2018 / (High School or above) / 11 minutes

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SHOW ME SCIENCE ADVANCED - CHEMISTRY & PHYSICS: CHEMISTRY - PERIODIC TABLE OF ELEMENTS PART III - LI & BE

As we continue our history of the Periodic Table organizational system and discovery of the elements, this program examines the elements lithium and beryllium. The characteristics of alkali metals and alkali earth metals are discussed in detail, with the help of graphics and animation demonstrating their similarities and differences. Students will learn why elements are organized into specific groups and their relations to the rows and columns of the periodic table.

DVD / 2015 / (High School or above) / 9 minutes

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SHOW ME SCIENCE ADVANCED - CHEMISTRY: PERIODIC TABLE OF ELEMENTS - POTASSIUM (K) AND MAGNESIUM (MG)

The Periodic Table is organized with elements specified in rows, or periods, according to increasing atomic number. Metals are on the left of the periodic table, while nonmetals are located on the right. Some in the middle are called metalloids because they have characteristics of both metals and nonmetals. The periodic table is purposely arranged into vertical classifications called groups. Columns of elements help define element groups. Some of the notable groups of elements include the noble gases (column 18), the halogens (column 17), the alkali metals (column 1) and the alkaline earth metals (column 2). The transition metals are located in the center of the periodic table. They include many of the common metals, such as copper, iron, silver and gold. The two rows below the main body of the table are called the lanthanide and actinide series. They include the very heavy metallic elements, such as uranium and plutonium. This program goes in depth regarding the elements potassium (K) and magnesium (Mg) and their roles in the health of the human body. Potassium helps to control the proper balance of fluids in cells, helps with the contraction of muscles, and is involved in the transmission of chemical messages between nerve cells. Potassium aids in digestion of food, and in the proper function of the eyes. Magnesium is needed for more than 300 biochemical reactions in the body. It helps maintain normal muscle and nerve function, keeps heart rhythm steady, supports a healthy immune system, and keeps bones strong.

DVD / 2013 / (High School or above) / 15 minutes

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SHOW ME SCIENCE ADVANCED - CHEMISTRY: PERIODIC TABLE OF ELEMENTS

Chemistry has an impact on every aspect of our daily lives. The most important chemistry reference is the Periodic Table of the Elements. By providing a logical, mathematical method of organization, the table has become a critical tool for students, teachers and scientists around the globe. This program explores the discoveries that led up to the organization of the periodic table and how it is presently organized. It introduces and explores several elements (Hydrogen and Titanium) and their effect on our daily lives and the environments in which they occur.

DVD / 2012 / (High School or above) / 12 minutes

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SHOW ME SCIENCE ADVANCED - NATURES CHEMICAL WONDER: ACID CAVES EXPLORED

Deep in Southern Mexicos jungle, the Villa Luz limestone caves support an ecosystem that thrives in a highly poisonous, acidic environment. This rare type of cave is found in few spots on Earth. The Villa Luz, is known for the bacteria in its thermal sulphur springs that produce hydrogen sulfide gas. When the gases form bonds with oxygen, the result is sulfuric acid. The acid eats away at the cave walls, constantly altering the patterns in the cretaceous limestone. All life forms, from microbial colonies to spiders, fish and bats, are interdependent upon the toxic soup of water, sulphur-oxide and hydrogen monoxide for survival. Surprisingly, the caves are home to spiders, bats, and a unique fish species referred to as the Cave Molly. The caves are also well known for their snottites, which are mucous-like formations that resemble stalactites. Descending into the caves is very dangerous as there are potentially lethal levels of hydrogen sulfide gas. Researchers carefully plan expeditions into the caves to better understand these rare ecosystems and must wear respirators and protective clothing as they enter the cave system in their attempt to document and understand the deadly ecosystem.

DVD / 2012 / (High School or above) / 16 minutes

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CHEMISTRY TUTOR, THE: ATOMIC MASS OF AN ELEMENT

This program covers the very important topic of atomic mass of an element. We begin by discussing the structure of the atom and how this can be used to arrive at a number that represents the relative mass of the atom. This quantity will be used in virtually every calculation in chemistry. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: ATOMIC NUMBER, MASS NUMBER & ISOTOPES PART 1

This program covers the very important topics known as atomic number, mass number, and isotopes. We begin by discussing the structure of the atom and how the atomic number is used to organize the periodic table. We discuss the mass number of an atom and how to write this down with the chemical symbol and the atomic number. Finally, we discuss isotopes and give examples that show that isotopes exist in nature and give rise to atoms with similar properties but different masses. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: ATOMIC NUMBER, MASS NUMBER & ISOTOPES PART 2

This program covers the very important topics known as atomic number, mass number, and isotopes. We begin by discussing the structure of the atom and how the atomic number is used to organize the periodic table. We discuss the mass number of an atom and how to write this down with the chemical symbol and the atomic number. Finally, we discuss isotopes and give examples that show that isotopes exist in nature and give rise to atoms with similar properties but different masses. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 34 minutes

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CHEMISTRY TUTOR, THE: ATOMIC THEORY OF MATTER PART 1

This program covers part 1 of the very important topic of the atomic theory of matter. We discuss how atoms combine together to form new compounds. Students review the law of conservation of mass and how the mass of the substances at the beginning of a reaction must equal the mass of the products of the reaction. We conclude by discussing the law of multiple proportions and how this law can predict how new compounds will form in nature. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: ATOMIC THEORY OF MATTER PART 2

This program covers part 2 of the very important topic of the atomic theory of matter. We discuss how atoms combine together to form new compounds. Students review the law of conservation of mass and how the mass of the substances at the beginning of a reaction must equal the mass of the products of the reaction. We conclude by discussing the law of multiple proportions and how this law can predict how new compounds will form in nature. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: ATOMIC THEORY OF MATTER PART 3

This program covers part 3 of the very important topic of the atomic theory of matter. We discuss how atoms combine together to form new compounds. Students review the law of conservation of mass and how the mass of the substances at the beginning of a reaction must equal the mass of the products of the reaction. We conclude by discussing the law of multiple proportions and how this law can predict how new compounds will form in nature. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: DENSITY

This program covers the very important topic of density as it relates to chemistry. We begin by discussing mass and volume and conclude by showing that the ratio of these quantities (mass per unit volume) is a very useful way to compare substances and is known as density. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: HYDRATE COMPOUNDS

This program covers the very important topic of hydrate compounds. We begin by discussing what a hydrate compound is and why they exist in nature. We discuss how to name hydrate compounds using numerous examples. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: INTRODUCTION TO CHEMISTRY

This program provides an introduction to chemistry. We begin by discussing how chemistry touches every part of everyday life and give several examples of basic chemical reactions that students come into contact with regularly. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: IONIC COMPOUNDS

This program covers the very important topic of ionic compounds. We discuss how ionic compounds form and how to predict ahead of time what the chemical formula will be when given the atoms that form the ionic compound. We spend a great deal of time discussing how to name ionic compounds. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: IONIC COMPOUNDS WITH POLYATOMIC IONS

This program covers the very important topic of ionic compounds with polyatomic ions. We discuss the concept of a polyatomic ion as simply the grouping of atoms that has a net charge associated with it. We then discuss how these polyatomic ions can form ionic compounds with other elements. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: IONS AND IONIC CHARGE

This program covers the very important topic of ions and ionic charge. We begin by discussing the concept of an ion and how it relates to a neutral atom. We then discuss how to calculate the ionic charge on an atom with practical examples. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: NAMING MOLECULAR COMPOUNDS

This program covers the very important topic of naming molecular compounds. We begin by discussing how molecular compounds form and how they arise in nature. We discuss in detail the naming method for molecular compounds including all of the prefixes necessary to name any molecular compound. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: OVERVIEW OF THE PERIODIC TABLE

This program covers the very important topic of the periodic table. We give an overview of how the periodic table is organized including the periods, groups, noble gases, metals, nonmetals, transition elements, and more. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: SIGNIFICANT FIGURES IN CALCULATIONS

This program covers the very important topic of significant figures in chemistry calculations. It is important to understand that the number of decimal places in the calculated answer to a problem should take into account how many decimals were provided in the provided statement. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: TEMPERATURE

This program covers the very important topic of temperature. We discuss temperature scales and why temperature is important when discussing chemical reactions. We also discuss how to convert from one temperature scale to the other. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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CHEMISTRY TUTOR, THE: UNITS AND UNIT CONVERSIONS

This program covers the important topic of units and unit conversions in chemistry. We begin by discussing the primary units that will be used throughout the course. Next, we illustrate a very powerful technique to convert from one unit to another that the student will use in virtually every chemistry problem. The entire lesson is taught by working example problems beginning with the easier ones and gradually progressing to the harder problems. Emphasis is placed on giving students confidence in their skills by gradual repetition so that the skills learned in this section are committed to long term memory.

DVD / 2011 / (Grades 9-College, Adults) / 20 minutes

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BIOSPHERE, THE

Global warming, ozone depletion and acid rain all make headlines and the evening news. In order to understand these and other global environmental problems, students need to understand what biologists call the biosphere.

Part 1. A Brief History of the Biosphere.How did the biosphere come to be? Traces the history of four billion years of the growth of the atmosphere and of changing life on planet earth.

Part 2. The Biosphere Today. Gives the student a clear, dramatic picture of the scientific concepts needed to understand the biosphere today.

In The Biosphere the keys to scientific literacy include:aerobic, ages of earth, anaerobic, amino acids, ammonia, bacteria, biosphere, carbon dioxide,chemical cycles, ecosystem, enzymes, evolution, fossil fuels, Gaia, global warming, greenhouse effect, homeostasis, methane, meteor, molecules,natural selection, niche, nitrogen, nitrogen cycle, nucleic acids, oxygen, ozone, phosphorus, photosynthesis, pollution, proteins,recycling, respiration, sulfur.


DVD (Closed Captioned) / 2007 / (Secondary, College) / 38 minutes

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ECOSYSTEMS

What is ecology? How can it help us understand the world we live in? A 2005 revised and updated program ideal for life science and environmental studies.

Part 1. From Nature Study to Ecology. The naturalist tradition of Henry David Thoreau is contrasted with the hard science tradition of modern quantitative ecology. New video footage from Walden Pond and from Silver Springs, Florida, where Eugene and Howard Odum did their pioneering work in the 1950s.

Part 2. The Web of Life. Carefully outlines concepts used by ecologists to study ecosystems today. Program includes a look at how human values play key roles in environmental choices.

In Ecosystems the keys to scientific literacy include: abiotic, acid rain, biosphere, Rachel Carson, chemical cycles, consumer, decomposer, ecology, food chains, greenhouse effect, natural selection, niche, ozone, parasite, photosynthesis, predator, producer, quantitative, recycling, species, thermodynamics, Thoreau, toxic wastes.


DVD (Closed Captioned) / 2005 / (Secondary, College) / 36 minutes

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CHEMICAL CYCLES IN THE BIOSPHERE

DVD footage from around the world and updated computer graphics show how chemicals cycle within the biosphere. Emphasized are the oxygen-carbon dioxide cycle, the nitrogen cycle, the water cycle, acid rain and how toxic chemicals can affect the biosphere.

DVD / 2004 / (Secondary, College) / 27 minutes

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GENE, THE

Clearly and simply presents basic information on one of the most important concepts in modern science-the gene. New computer animations help clarify the concepts. Includes guided questions and quizzes to help teachers reinforce concepts recommended in the National Science Standards.

Part 1. How Genes Were Discovered. Dramatizes the history of genetic discovery from Mendel in his monastery garden to Watson and Crick at the Cavendish Laboratory in England.

Part 2. What Is a Gene and How Does It Work? Outlines the basic picture we have today of what a gene is and how it works. Includes new material on cloning and the human genome project.

In The Gene the keys to scientific literacy include: adenine, amino acids, biochemist, chromosomes, cloning, Francis Crick, cytosine, differentiation, DNA, double helix, enzymes, Rosalind Franklin, gene gun, genetics, genome project, guanine, meiosis, Gregor Mendel, mitosis, mutation, ovary, protein, restriction enzyme, RNA, thymine, James Watson.


DVD (Closed Captioned) / 2004 / (Secondary, College) / 40 minutes

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TOXIC WASTES

Students are often bewildered by news stories about the latest toxic waste hazards. With this popular program, newly updated in 2004, you can help your students better understand the science of toxicology.

Part 1. A History of Toxic Wastes in the Biosphere. Shows how the "good old days" had serious toxic waste problems too. How they solved past crises gives clues for solving our toxic waste problems today.

Part 2. Toxic Wastes Today. Explains the basic scientific concepts needed to convert fear into intelligent action.

In Toxic Wastes the keys to scientific literacy include: acid rain, AIDS, antitoxins, arsenic, asbestos, bacteria, biosphere, Black Death, carcinogen, chemical cycles, Chernobyl, dioxin, EPA, epidemic, food chains, genetics, landfills, Love Canal, mercury, mutagen, natural carcinogens, oil spills, parts per billion, Pasteur, PCB, pesticides, plutonium, pollution, radioactive wastes, recycling, smallpox, smoking, syphilis, Three Mile Island, vaccine.


DVD / 2004 / (Secondary, College) / 40 minutes

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MODERN BIOLOGY: AN INTRODUCTION

Begin your course in biology or life science with this program. Or use it to review or sum up. Students will learn how intertwined all the sciences are today on the frontiers of biology.

Part 1 takes your students on a brief but informative tour of the history of biology. Special sttention is paid to pioneers like Darwin, Mendel, Pasteur and, in our time, Watson and Crick.

In Part 2 students meet some outstanding biologists of today. Featured are two of the founders of modern ecology, Eugene and Howard Odum, geneticist Richard Burgess, biochemist Bruce Ames and others.


DVD / 2003 / (Secondary, College) / 54 minutes

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MODERN CHEMISTRY: AN INTRODUCTION

Give your students an overview of chemistry-yesterday, today and tomorrow. This live-action program includes a segment on the potential of buckyballs, the soccer-ball-shaped molecules that promises a whole new world of chemistry in the 21st century.

Part 1 is a short history of chemistry from the alchemists to the 20th century wizards. Part 2 includes exclusive interviews with outstanding modern chemists including Bassam Shakashiri, Regina Murphy, Spencer Silver (who invented the Post-It Note adhesive for 3M), Donald Huffman (who first made buckyballs), and others.


DVD (Closed Captioned) / 2003 / (Secondary, College) / 54 minutes

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ECOSYSTEM CYCLES: ECOSYSTEMS ON EARTH/FOOD CHAINS IN BIOSPHERE/CHEMICAL CYCLES IN BIOSPHERE

Ecosystems on Earth
What is the state of the world's ecosystems as the 21st century begins? A primer on ecosystem problems and opportunities with the stress on new efforts to save endangered species, new efforts to avert global warming and new efforts to preserve and restore to health all ecosystems, including agricultural and urban ones.

Food Chains in the Biosphere
Students will learn how producers, consumers, decomposers and the abiotic elements are connected in ecosystems and how ecosystems make up a biosphere. Program features new computer graphics and live-action video illustrating important concepts in modern ecology.

Chemical Cycles in the Biosphere
Video footage from around the world and updated informative computer graphics show how chemicals cycle within the biosphere. Emphasized are the oxygen-carbon dioxide cycle, the nitrogen cycle, the water cycle, acid rain and how toxic chemicals can affect the biosphere.

On Ecosystems Cycles DVD you can have easy access to keys to scientific literacy that include:
Chemicals in the biosphere, oxygen-carbon dioxide cycle, photosynthesis, respiration, nitrogen cycle, organic fertilizers, water cycle, chemicals of life, what is the biosphere?, life cycles in biosphere, producers, food pyramids, food chains, food webs, decomposers, energy flow, agricultural and urban ecosystems, homeostasis, chemical pollution, chemical progress, global warming, species extinction.


DVD (Closed Captioned) / 2001 / (Secondary, College) / 61 minutes

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ECOSYSTEMS IN ACTION 2: A NEW ENGLAND POND/THE GREAT LAKES ECOSYSTEM/THE WEB OF LIFE

A New England Pond
Some of the best work in ecology has been done on small fresh water pond ecosystems. This live-action video uses a small New England pond to teach basic concepts in ecosystem science. Food webs are illustrated, the abiotic-producer-consumer-decomposer cycles, problems of acid rain and pond succession are also stressed.

The Great Lakes Ecosystem
The largest chain of fresh water lakes in the world has special ecological problems of its own. This live-action video explains some of the challenges today. Stressed are the sea lamprey, toxic wastes in the lakes, the coming of the zebra mussel and the ruffe fish.

The Web of Life
Explains the concepts used by ecologists today to study ecosystems. Food chains, food webs, cycling of elements, toxic wastes and more.

On Ecosystems in Action 2 DVD you can have easy access to keys to scientific literacy that include:
Pollution from mining, zebra mussels, food chains and eutrophication, chemical pollutants, european ruffe, ecology and ecosystems, energy flow in a small pond, food pyramids, niches, food webs, cycling of matter, succession, acid rain, what is ecology?, energy flow in all ecosystems, producers & consumers, food chains, recycling of matter, environmental problems, biosphere problems.


DVD (Closed Captioned) / 2001 / (Secondary, College) / 66 minutes

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